Reese Witherspoon and Ryan Philippe
Once they were Young Hollywood's golden couple. Hunky Ryan Philippe and overachiever Reese Witherspoon met at her 21st birthday party - he crashed it - and they went on to get married and have two children - Ava and Deacon. Let's not forget they also starred in classic teen movie Cruel Intentions
Then, amid persistent rumours about Ryan cheating with actress Abbie Cornish in 2006 (he subsequently had a relationship with her), the dream was over after seven years of marriage. Reese enjoyed herself after their split, dating Jake Gyllenhaal, before marrying Hollywood agent Jim Toth.
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